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Revision Notes on Thermodynamics. Thermodynamics:-It is the branch of physics which deals with process involving heat, work and internal energy.Thermodynamics is concerned with macroscopic behavior rather than microscopic behavior of the system.

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Theoretical background. The acid dissociation constant for an acid is a direct consequence of the underlying thermodynamics of the dissociation reaction; the pK a value is directly proportional to the standard Gibbs free energy change for the reaction. The value of the pK a changes with temperature and can be understood qualitatively based on Le Châtelier’s principle: when the reaction is.

Dec 12, 2016. 19.2: Entropy and the Second Law of Thermodynamics. ice melting at 0°C; salt crystallizing from a saline solution; evaporation. H2(g)+12O2(g)→H2O(l); 2H2( g) + C2H2(g) → C2H6(g); (CH3)2O(g) + H2O(g) → 2CH3OH(l).

In thermodynamic models, the system and surroundings comprise everything, 2text{CH}_3text{OH}(l). Solution The value of the standard entropy change is. 100.6 J/K. 6. (a) −198.1 J/K; (b) −348.9 J/K. 8. As ΔSuniv < 0 at each of these.

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In a chemical reaction, chemical equilibrium is the state in which both reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. Usually, this state results when the forward reaction proceeds at the same rate as the reverse reaction.

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